catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]

نویسنده

  • Jinfang Zhang
چکیده

The title compound, {[Cu(2)I(2)(C(12)H(8)N(6))(C(18)H(15)P)(2)]·2CH(3)CN}(n), contains centrosymmetric dinuclear Cu(2)I(2)(PPh(3))(2) units bridged by 3,6-bis-(4-pyrid-yl)-1,2,4,5-tetra-zine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The distorted tetra-hedral Cu(I) atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetra-zine ligand and one terminal triphenyl-phosphine P-atom donor. The Cu⋯Cu distance is 2.8293 (12) Å, implying a weak Cu⋯Cu inter-action.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010